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Geometric parameters of transition states of radical abstraction reactions with C...H...C reaction center

✍ Scribed by E. T. Denisov; A. F. Shestakov; T. G. Denisova; N. S. Emel"yanova


Book ID
111607677
Publisher
Springer
Year
2004
Tongue
English
Weight
478 KB
Volume
53
Category
Article
ISSN
1573-9171

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Reaction of CF3 radicals with C2H6
✍ Haluk Arican; Neville L. Arthur πŸ“‚ Article πŸ“… 1986 πŸ› John Wiley and Sons 🌐 English βš– 333 KB πŸ‘ 1 views

The hydrogen transfer reaction between C2H6 and CFs radicals, generated by the photolysis of CF31, has been studied in the temperature range 298-617 K. The rate constant, based on the value of 1013 36 cm3 mo1-l s-' for the recombination of CFs radicals, is given by log kp = (11.90 2 0.09) -(33230 \_