Metathesis of Alkyl Radicals and Alkenes
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Priv.-Doz. Dr. JΓΌrgen O. Metzger
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Article
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1986
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John Wiley and Sons
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English
β 236 KB
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pretation is supported by the significantly lengthened Si-C bonds (I99 pm compared with 187 pm for the single bond) and the expanded angle at the tertiary C atoms (C-C-C between 104.2 and 106.5", Si-C-C between 110.9 and 114.8"). The Si-Si distance in 1 corresponds to a Pauling bond order of 0.45 an