Reaction CH 3 + OH Studied over the 294–714 K Temperature and 1–100 bar Pressure Ranges
✍ Scribed by Sangwan, Manuvesh; Chesnokov, Evgeni N.; Krasnoperov, Lev N.
- Book ID
- 127165843
- Publisher
- American Chemical Society
- Year
- 2012
- Tongue
- English
- Weight
- 722 KB
- Volume
- 116
- Category
- Article
- ISSN
- 1089-5639
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📜 SIMILAR VOLUMES
Rate constants for the reaction of OH radicals vlith COS. CSz and CII~SCHJ, which are invo!ved in the glohal sulfur cycle, iI;IVC been determined over the temperature range 299-430 K uGng a flash ps hotolysis-resonance fluorcsccnu: tcchmque. For COS and CS2 upper limits at room tcmyzraturc of k(COS)
Rate constants for the reactions of OH radicals with CH,CHF, and CHCI,CF, have been determined over the temperature range 295-388 K and a total pressure of 1 atm. The OH rate data were obtained using the absolute rate technique of pulse radiolysis combined with kinetic spectroscopy.