## Abstract The reaction between methyl and hydroxyl radicals has been studied in reflected shock wave experiments using narrow‐linewidth OH laser absorption. OH radicals were generated by the rapid thermal decomposition of tert‐butyl hydroperoxide. Two different species were used as CH~3~ radical
Product Study of the Reaction of CH 3 with OH Radicals at Low Pressures and Temperatures of 300 and 612 K †
✍ Scribed by Fockenberg, Christopher; Weston,, Ralph E.; Muckerman, James T.
- Book ID
- 127330970
- Publisher
- American Chemical Society
- Year
- 2005
- Tongue
- English
- Weight
- 296 KB
- Volume
- 109
- Category
- Article
- ISSN
- 0022-3654
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📜 SIMILAR VOLUMES
Recently, Atkinson et al. have developed a more sophisticated approach than simple additivity to determine group rate constants a t room temperature for reactions of OH radicals with alkanes. In this article, use is made of reliable experimental data a t room temperature and at 753 K to determine te
Absolulc KIIC constants for the rcac11on ofOH WIII acctylcnc wcrc dctcrmmcd at 297 and 419 K for thu 101.d pru~rc\ ol'20-403 Torr usmg a flash photolysa-rcsonancc lluorcsccnre tcchmquc The rate coclTic~cnt k was found to bc pwrurc dcpcndcnt below 200 Torr at both 297 and 429 K, but \\a m the high-pr