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Reaction between Methyl Oleate and Mercuric Acetate in Hot Acetic Acid

✍ Scribed by Toyama, Y. ;Takaoka, K.

Publisher: John Wiley and Sons
Year: 1964
Weight: 538 KB
Volume: 66
Category: Article
ISSN: 0931-5985
DOI: 10.1002/lipi.19640661203

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✦ Synopsis

Tokyollapan

Methyl oleate was reacted with mercuric acetate in hot acetic acid to give mercuraled adducts which, however, decomposed with the liheration of metallic mercury as the reaction pr0ceede.d further. The oily product containing no mercury was found to consist of methyl acetoxy-octadecenoates together with unchanged methyl oleate.. From the results of the ozonolysis of the methyl-hydroxy-octadecenoates and conjugated octadecadienoates derived from the methyl acetoxy-octadecenoates, it was concluded that the methyl acetoxy-octadecenoates contain 10-acetoxy-8-octadecenoate, 9-acetoxy-lO-octadecenoate, ll-acetoxy-9-octadecenoate and 8-acetoxy-9-octadecenoate.

Reaktion zwischen Methyloleat und Quecksilberacetat in heiDem Eisessig

Methyloleat wurde mit Quecksilberacetat in heiBem Eisessig zu merkurierten Addukten umgesetzt,

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