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Rb2Au6Sb4S10: a novel sulfosalt with two different interpenetrating anionic frameworks: [Au3Sb4S8]− and [Au3S2]−

✍ Scribed by Hanko, Jason A.; Kanatzidis, Mercouri G.


Book ID
120559450
Publisher
Royal Society of Chemistry
Year
1998
Tongue
English
Weight
75 KB
Volume
6
Category
Article
ISSN
1359-7345

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3 motif. Upon further inspection, it is observed that the Au + centers in (V) aggregate to form a column that runs along the c-axis. The presence of a sharp optical gap of 1.37 eV suggests that (V) is a semiconductor. -(HANKO,

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## Abstract As revealed by single crystal XRD compounds (II) and (VI) crystallize in the triclinic space group P$\bar 1$ with Z = 2, (IV) in the monoclinic space group P2~1~/m with Z = 4, and (V) in the monoclinic space group P2~1~/n with Z = 4.