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Synthesis and Characterization of Gold(I) Complexes with the Ligand 1,2-Dithiolate- o -carborane. Crystal Structures of [Au 2 (μ-S 2 C 2 B 10 H 10 )(PPh 3 ) 2 ], [Au 2 (μ-S 2 C 2 B 10 H 10 )(μ-{(PPh 2 ) 2 (CHCH)}], and [Au 2 (μ-S 2 C 2 B 10 H 10 )(μ-{(PPh 2 ) 2 (C 6 H 4 )}]

✍ Scribed by Crespo, Olga; Gimeno, M. Concepción; Jones, Peter G.; Ahrens, Birte; Laguna, Antonio


Book ID
125967517
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
215 KB
Volume
36
Category
Article
ISSN
0020-1669

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Synthesis of Silver(I) Complexes with th
✍ Bembenek, Eberhard ;Crespo, Olga ;Concepción Gimeno, M. ;Jones, Peter G. ;Laguna 📂 Article 📅 1994 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 549 KB

Silver(1) complexes I Bis(diphenylphosphany1)-o-carborane I o-Carborane Silver(1) perchlorate or nitrate react readily with bis(di-phenylphosphany1)-o-carborane to give the complexes [AgX((PPh2)2C2BloHlo)1 [X = C104 (l), NO3 (2)]. The perchlorate ligand is weakly bound to the silver atom and thus ca