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Gold(I) Complexes with the nido -Diphosphino Ligand [7,8-(Ph 2 P) 2 -7,8-C 2 B 9 H 10 ] - . Preparation of the First Metallocarborane Complex of this Ligand. Crystal Structures of [Au{(PPh 2 ) 2 C 2 B 9 H 10 }(PPh 3 )]·CH 2 Cl 2 and [Au 2 {(PPh 2 ) 2 C 2 B 9 H 10 } 2 {(PPh 2 ) 2 (CH 2 ) 3 }]·3Me 2 CO

✍ Scribed by Crespo, Olga; Gimeno, M. Concepción; Jones, Peter G.; Laguna, Antonio


Book ID
127056104
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
175 KB
Volume
35
Category
Article
ISSN
0020-1669

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Synthesis of Silver(I) Complexes with th
✍ Bembenek, Eberhard ;Crespo, Olga ;Concepción Gimeno, M. ;Jones, Peter G. ;Laguna 📂 Article 📅 1994 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 549 KB

Silver(1) complexes I Bis(diphenylphosphany1)-o-carborane I o-Carborane Silver(1) perchlorate or nitrate react readily with bis(di-phenylphosphany1)-o-carborane to give the complexes [AgX((PPh2)2C2BloHlo)1 [X = C104 (l), NO3 (2)]. The perchlorate ligand is weakly bound to the silver atom and thus ca