Rational Syntheses and Structural Characterization of Sulfur-Rich Phosphorus Polysulfides: α-P2S7 and β-P2S7
✍ Scribed by Thomas Rödl; Dr. Richard Weihrich; Julia Wack; Prof. Dr. Jürgen Senker; Prof. Dr. Arno Pfitzner
- Publisher
- John Wiley and Sons
- Year
- 2011
- Tongue
- English
- Weight
- 921 KB
- Volume
- 50
- Category
- Article
- ISSN
- 0044-8249
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📜 SIMILAR VOLUMES
\(\mathrm{RbVP}_{2} \mathrm{~S}_{7}\) has been obtained as black platelets by heating the elements in stoichiometric proportions at \(550^{\circ} \mathrm{C}\) under vacuum in evacuated silica tubes for 21 days. It crystallizes in the monoclinic symmetry, space group \(C 2\), with the parameters \(a=
Reaction of [Mo 3 Y(m-S) 3 (dtp) 4 (H 2 O)] (Y O, S; dtp S 2 P(OC 2 H 5 ) 2 À ) with HgI 2 gave the novel compound {[Mo 3 S 7 (dtp) 3 ] 4 ´I}{(HgI 3 ) 3 } ´4 H 2 O (1), which contains a {[Mo 3 S 7 (dtp) 3 ] 4 ´I} tetramer and (HgI 3 ) À . Compound 1 has been characterized by IR, Raman, UV/Vis, and N