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ChemInform Abstract: Syntheses of the syn and anti α-Amino-β-hydroxy Acids of Vancomycin: (2S,3R)- and (2R,3R)-p-Chloro-3-hydroxytyrosines.

✍ Scribed by A. GIRARD; C. GRECK; D. FERROUD; J. P. GENET

Publisher
John Wiley and Sons
Year
2010
Weight
36 KB
Volume
28
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Baker′s Yeast Media
ChemInform Abstract: Baker′s Yeast Mediated Enantiospecific Synthesis of anti-(2R,3R)-p-Chloro-3-hydroxytyrosine: An α-Amino-β-hydroxy Acid of Vancomycin.
✍ N. W. FADNAVIS; S. K. VADIVEL; M. SHARFUDDIN; U. T. BHALERAO 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB

Baker's Yeast Mediated Enantiospecific Synthesis of anti-(2R,3R)p-Chloro-3-hydroxytyrosine: An α-Amino-β-hydroxy Acid of Vancomycin. -The synthesis of the protected derivative (V) is achieved via baker's yeast-mediated reduction of the α-azido-β-keto ester (II) at pH 4.0. At pH 7.0 the enantioselect