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Rates of recombination of free radicals. V. The tert-butyl radical

✍ Scribed by R. Hiatt; S. W. Benson

Publisher
John Wiley and Sons
Year
1973
Tongue
English
Weight
580 KB
Volume
5
Category
Article
ISSN
0538-8066

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✦ Synopsis

Abstract

Analysis of the products from a vapor‐phase mixture of EtI and t‐BuI, in which free radicals were generated thermally, has yielded a rate constant for the recombination of 2__t__‐Bu⋅ of 10^5.4^ M^−1^ sec^−1^ at 100°C. The close agreement between this and other recent estimations from vapor‐phase work is noted, as is the disparity between these values and those on the order of 10^9^ M^−1^ sec^−1^ obtained in solution.

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