The thermal decomposition of acetonitrile in the temperature range is modeled with a reaction scheme containing 23 species and 43 elementary 1350-1950 K reactions. Values of which were reported in a previous investigation {[product] /[CH CN] }/t, t 3 0 are computed with this scheme at intervals and
Kinetic modeling of tert-butyl radical decomposition reaction
β Scribed by Xiaobo Zheng; Paul Blowers
- Publisher
- American Institute of Chemical Engineers
- Year
- 2006
- Tongue
- English
- Weight
- 226 KB
- Volume
- 52
- Category
- Article
- ISSN
- 0001-1541
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π SIMILAR VOLUMES
The temperature dependence of the rate coefficients for the OH radical reactions with iso-propyl acetate (k 1 ), iso-butyl acetate (k 2 ), sec-butyl acetate (k 3 ), and tert-butyl acetate (k 4 ) have been determined over the temperature range 253-372 K. The Arrhenius expressions obtained are: were
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