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Rates of hydrogen atom abstraction from benzyltrimethylsilanes by bromine and tert-butoxy radical. The question of the stability of the .alpha.-(trimethylsilyl)benzyl radical

✍ Scribed by Swenton, John S.; Platz, Matthew; Venham, Lanny D.


Book ID
127118385
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
706 KB
Volume
53
Category
Article
ISSN
0022-3263

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## Abstract Measurements of rates of oxygen absorption and steady‐state peroxy radical concentrations for the autoxidation of tetralin in the presence of __tert__‐butyl hydroperoxide have shown that the rate constant for reaction of the __tert__‐butylperoxy radical with tetralin at 60Β°C is approxim