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Dramatic Solvent Effects on the Absolute Rate Constants for Abstraction of the Hydroxylic Hydrogen Atom from tert-Butyl Hydroperoxide and Phenol by the Cumyloxyl Radical. The Role of Hydrogen Bonding

✍ Scribed by Avila, David V.; Ingold, K. U.; Lusztyk, J.; Green, W. H.; Procopio, D. R.


Book ID
111964286
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
268 KB
Volume
117
Category
Article
ISSN
0002-7863

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## Abstract Measurements of rates of oxygen absorption and steady‐state peroxy radical concentrations for the autoxidation of tetralin in the presence of __tert__‐butyl hydroperoxide have shown that the rate constant for reaction of the __tert__‐butylperoxy radical with tetralin at 60Β°C is approxim