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The Abstraction of Hydrogen Atoms from Liquid Hydrocarbons by t-Butoxy Radicals

✍ Scribed by Williams, A. L.; Oberright, E. A.; Brooks, J. W.


Book ID
120483974
Publisher
American Chemical Society
Year
1956
Tongue
English
Weight
502 KB
Volume
78
Category
Article
ISSN
0002-7863

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Hydrogen atom abstraction from polypropy
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In order to elucidate the site of radical attack on polypropylene and polystyrene, the abstractions of hydrogen atoms by t-butoxy radicals and phenyl radicals have been studied by using a spin trapping technique. The r-butoxy radical abstracted tertiary hydrogen atoms selectively from polypropylene,

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## Abstract The kinetics of the gamma‐radiation induced free radical reactions in carbon tetrachloride solutions of 2,3‐dimethylbutane (DMB) were studied in the temperature range 32–118 Β°C. The kinetics of the following reactions were measured: and the following rate constants expression was obtai