The Abstraction of Hydrogen Atoms from Liquid Hydrocarbons by t-Butoxy Radicals
β Scribed by Williams, A. L.; Oberright, E. A.; Brooks, J. W.
- Book ID
- 120483974
- Publisher
- American Chemical Society
- Year
- 1956
- Tongue
- English
- Weight
- 502 KB
- Volume
- 78
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
In order to elucidate the site of radical attack on polypropylene and polystyrene, the abstractions of hydrogen atoms by t-butoxy radicals and phenyl radicals have been studied by using a spin trapping technique. The r-butoxy radical abstracted tertiary hydrogen atoms selectively from polypropylene,
## Abstract The kinetics of the gammaβradiation induced free radical reactions in carbon tetrachloride solutions of 2,3βdimethylbutane (DMB) were studied in the temperature range 32β118 Β°C. The kinetics of the following reactions were measured: and the following rate constants expression was obtai