The rate constant of the reaction, OH + NH3 -+ Hz0 + NH2, has been measured at temperatures between 230 and 490'K using time-resolved resonance absorption to observe the concemytion of OH radicals..An Arrhenius expression, kI = 2.3 X lO\_" exp(-1.6 kcai mole-'/RT) cm3 molecule-' set , was obtained.
โฆ LIBER โฆ
Rate of reaction of OH With HNO 3
โ Scribed by Wine, P. H.; Ravishankara, A. R.; Kreutter, N. M.; Shah, R. C.; Nicovich, J. M.; Thompson, R. L.; Wuebbles, D. J.
- Book ID
- 119718972
- Publisher
- American Geophysical Union
- Year
- 1981
- Tongue
- English
- Weight
- 874 KB
- Volume
- 86
- Category
- Article
- ISSN
- 0148-0227
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The absolute rate constant for the OH + HCI reaction has been measured from 240 to 295 K utilizing the techniques of laser/flash photolysis-resonance fluorescence. The HCl concentrations were monitored continuously by ultraviloet and infrared spectrophotometry. The results can be fit to the followin