Copolymers of N-vinylcarbazole (NVC) and N,N-dimethylaminoethyl methacrylate (DMAEMA) were prepared by free-radical polymerization in a toluene solution at 60ΠC using 2,2 -azobisisobutyronitrile (AIBN) as an initiator. The reactivity ratios of both monomers were calculated using the extended Kelen-T
Rate of radical polymerization of N,N-dimethylaminoethyl methacrylate in cyclohexane
β Scribed by Kiyohisa Fujimori; Anthony S. Brown; Marion J. Costigan; Ian E. Craven
- Publisher
- Springer
- Year
- 1984
- Tongue
- English
- Weight
- 161 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0170-0839
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## Abstract The specific features of freeβradical polymerization of methyl methacrylate in the presence of a new initiating system, benzoyl peroxideβ__N,N__βdimethylβ__N__β(methylferrocenyl)amine, are studied. Mutual influence of ferrocenylβ and amine groups on kinetic parameters of polymerization
The polymerization of N-methylmethacrylamide (NMMAm) with azo-bis-isobutyronitrile (AIBN) was kinetically investigated in cyclohexane which has a small affinity for NMMAm monomer. The polymerization proceeded heterogeneously. The polymerization rate (Rp) was expressed by the following equation: The