Analysis of polymerization rates in radical polymerization with primary radical termination of some methacrylates
โ Scribed by Ito, Katsukiyo
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1971
- Tongue
- English
- Weight
- 161 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0449-296X
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๐ SIMILAR VOLUMES
## Abstract Without knowledge of the familiar geometric mean, the following equation was derived for the radical polymerization with primary radical termination under the condition that reaction between primary radicals is negligible: where both __A__ and __B__ are constants depending on various r
Polymerization experiments with styrene in benzene at 60 ยฐ, initiated by benzoyl peroxide, covering a wide range of concentration of both monomer and initiator are reported; the results cannot be explained in terms of the classical rate relationship with Rp oc [I] tfz [MI. Deviations were reflected