Discussion of treatments for the kinetics of radical polymerization with primary radical termination

✍ Scribed by Katsukiyo Ito; Tatsuo Matsuda

• Publisher: John Wiley and Sons
• Year: 1970
• Tongue: English
• Weight: 197 KB
• Volume: 14
• Category: Article
• ISSN: 0021-8995
• DOI: 10.1002/app.1970.070140205

✦ Synopsis

Abstract

Without knowledge of the familiar geometric mean, the following equation was derived for the radical polymerization with primary radical termination under the condition that reaction between primary radicals is negligible:

where both A and B are constants depending on various rate constants. This equation was mathematically and experimentally dealt with.