We describe the basic kinetic features of "living" polymerizations controlled and regulated by persistent radicals or related species and by reversible atom transfer. In these systems a special kinetic phenomenon operates-the Persistent Radical Ef-fect. It is also known from selective organic synthe
Modeling the Effects of Primary Radicals in Free-Radical Polymerization
β Scribed by Vladimir Kaminsky; Michael Buback; Mark Egorov
- Publisher
- John Wiley and Sons
- Year
- 2002
- Tongue
- English
- Weight
- 123 KB
- Volume
- 11
- Category
- Article
- ISSN
- 1022-1344
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π SIMILAR VOLUMES
## Abstract A tubular reactor model for βlivingβ freeβradical polymerization is developed in this study. The model may be used as a tool to design efficient processes for tailored polymers from βlivingβ freeβradical polymerization. Examples presented include preparing bimodal polymers and copolymer
## Abstract Without knowledge of the familiar geometric mean, the following equation was derived for the radical polymerization with primary radical termination under the condition that reaction between primary radicals is negligible: where both __A__ and __B__ are constants depending on various r