The concept of effective crosslinking density proposed by Scanlan is extended to heterogeneously crosslinking polymer. A kinetic-statistical model of effective crosslinking density of the gel is developed in free-radical heterogeneously crosslinking polymerization. The model is applied to the vinyl
Gel growth in free radical crosslinking copolymerization: Effect of inactive gel radicals
β Scribed by Oguz Okay
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 110 KB
- Volume
- 9
- Category
- Article
- ISSN
- 1022-1344
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## Abstract __d__βBornyl methacrylate (BoMA) was chosen as a typical example of bulky monomethacrylate monomers, the polymerization of which led to the formation of a rigid polymer chain. To discuss the effect of primary polymer chain rigidity on intramolecular cyclization, we compared the solution
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