Postgel properties in the statistical crosslinking of heterochains. II. Free-radical crosslinking copolymerization
β Scribed by Hidetaka Tobita; Narito Tani; Takeshi Sakai
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 193 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0887-6266
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π SIMILAR VOLUMES
Two possible crosslinking mechanisms of PNVF gels. Scheme 1. Polymerization of NVF and hydrolysis of PNVF to PVAm.
The concept of effective crosslinking density proposed by Scanlan is extended to heterogeneously crosslinking polymer. A kinetic-statistical model of effective crosslinking density of the gel is developed in free-radical heterogeneously crosslinking polymerization. The model is applied to the vinyl
## Abstract __d__βBornyl methacrylate (BoMA) was chosen as a typical example of bulky monomethacrylate monomers, the polymerization of which led to the formation of a rigid polymer chain. To discuss the effect of primary polymer chain rigidity on intramolecular cyclization, we compared the solution