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Rate decelerations in the acetolysis of substituted cyclopentyl tosylates

✍ Scribed by Horn, David E.; Krapcho, A. Paul; Grenon, Brian J.


Book ID
120042805
Publisher
American Chemical Society
Year
1979
Tongue
English
Weight
457 KB
Volume
44
Category
Article
ISSN
0022-3263

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## Abstract Rates of the reactions between bromide ion and methyl tosylate have been determined in 12 solvents and extrapolated to infinite dilution. The data are correlated with __Parker__'s solvent activity coefficients by means of an empirical equation of the type: logk^s^ – logk^0^ = A log^0^Ξ³