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Polarity effects on the rate of solvolysis of 4-substituted cyclohexyl tosylates

โœ Scribed by Donald S. Noyce; Bruce N. Bastian; Richard S. Monson


Book ID
104213302
Publisher
Elsevier Science
Year
1962
Tongue
French
Weight
207 KB
Volume
3
Category
Article
ISSN
0040-4039

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Polar Effects in the Solvolysis of 4-Sub
โœ Cyril A. Grob; Roland Rich ๐Ÿ“‚ Article ๐Ÿ“… 1979 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 415 KB ๐Ÿ‘ 1 views

Hydrolysisofbicyclo[2.2.2]octylp-nitrobenzenesulfonate (14a,X =p-N02C6H4S03), and nineteen 4-R-substituted derivatives 14b-14 t in 70% aqueous dioxane yield the corresponding bicyclo [2.2.2]octanols 14 (X = OH), exclusively. The 7-center fragmentation to 1,4-dimethylidene-cyclohexane (15) is not obs