✦ LIBER ✦

Effects of two oppositely polarizing, distant substituents on the rate and stereochemistry of solvolysis of 2-adamantyl tosylate

✍ Scribed by Xie, Mei; Le Noble, W. J.

Book ID: 126805880
Publisher: American Chemical Society
Year: 1989
Tongue: English
Weight: 376 KB
Volume: 54
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo00277a019

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Polarity effects on the rate of solvolys

Polarity effects on the rate of solvolysis of 4-substituted cyclohexyl tosylates

✍ Donald S. Noyce; Bruce N. Bastian; Richard S. Monson 📂 Article 📅 1962 🏛 Elsevier Science 🌐 French ⚖ 207 KB

Polar Effects. X. Polar Substituent Effe

Polar Effects. X. Polar Substituent Effects in the Solvolysis of 3-Substituted 1-Adamantyl Bromides and Toluenesulfonates

✍ Cyril A. Grob; Bruno Schaub 📂 Article 📅 1982 🏛 John Wiley and Sons 🌐 German ⚖ 413 KB 👁 1 views

## Abstract The rate constants for 3‐substituted adamantyl __p__‐toluenesulfonates **3a**‐**3k** in ethanol/water 80:20 correlate well with the respective inductive substituent constants σ. The reaction constant ρ for the toluenesulfonates **3** is 10% larger than for the corresponding bromides **2

Substituent effects on the solvolysis of

Substituent effects on the solvolysis of 1,1-diphenyl-2,2,2-trifluoroethyl tosylates. Part III. Effects of electron-donating substituents in the fixed aryl moiety

✍ Mizue Fujio; Hyun-Joong Kim; Hiroshi Morimoto; Soo-Dong Yoh; Yuho Tsuno 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 190 KB 👁 1 views

The solvolysis rates of 1-aryl-1-(p-methoxyphenyl)-2,2,2-trifluoroethyl and 1-aryl-1-(p-phenoxyphenyl)-2,2,2-trifluoroethyl bromides and chlorides were conductimetrically measured at 25.0 °C in 80% aqueous ethanol. The solvolysis rates of 1-(p-methylphenyl)-fixed series were also set up to analyze t

Polar effects. Part 12. Inductivity and

Polar effects. Part 12. Inductivity and carbon participation in the solvolysis of 4-substituted 2-adamantyl arenesulfonates

✍ Cyril A. Grob; Gerhard Wittwer; K. Rama Rao 📂 Article 📅 1985 🏛 John Wiley and Sons 🌐 German ⚖ 480 KB 👁 1 views

## Abstract The rate constants (log __k__) for the solvolysis of 4^e^‐substituted 2^e^‐ and 2^a^‐adamantyl __p__‐nitrobenzenesulfonates **14** and **15**, respectively, in 80% EtOH correlate linearly with the respective inductive substituent constants σ. Therefore, relative rates are controlled by

ChemInform Abstract: Substituent Effects

ChemInform Abstract: Substituent Effects on the Solvolysis of 1,1-Diphenyl-2,2,2- trifluoroethyl Tosylates: Comparison Between Symmetrically Disubstituted and Monosubstituted Systems.

✍ M. FUJIO; H. MORIMOTO; H.-J. KIM; Y. TSUNO 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 30 KB

Effects of pressure and solvent on the s

Effects of pressure and solvent on the solvolysis of 2,2,2-triphenylethyl tosylate in alcohol-dioxane solutions

✍ Yoshiyuki Okamoto; Takefumi Yano 📂 Article 📅 1971 🏛 Elsevier Science 🌐 French ⚖ 151 KB