Recently3 we have examined 3,3,5,5-tetr8methylcyolohexanone (I) and bicyclo[3.2.1]octanone-3 (II) as models for the operation of the Reflex Effect. 4 Ae a continuation of this investigation we Were interested in the solvolysis of the tosylates derived from I and II. Accordingly, we have
โฆ LIBER โฆ
The Transition State in Acetolysis of Cyclohexyl Tosylate
โ Scribed by Saunders, William H.; Finley, Kay T.
- Book ID
- 126329994
- Publisher
- American Chemical Society
- Year
- 1965
- Tongue
- English
- Weight
- 281 KB
- Volume
- 87
- Category
- Article
- ISSN
- 0002-7863
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The apparent substituent effect on the acetolysis of 2-arylethyl tosylates was analyzed as a sum of two linear substituent effect relationships for aryl-assisted and -unassisted processes. The effect on the former process satisfied the LArSR Eq. with a unique r value of 0.6.