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Rate Constants of the Tactic Monomer Addition in the Anionic Polymerization of Methyl Methacrylate in THF with Cesium as Counterion

✍ Scribed by Müller, A. H. E.; Höcker, H.; Schulz, G. V.


Book ID
126922194
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
454 KB
Volume
10
Category
Article
ISSN
0024-9297

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Equilibria in the anionic polymerization
✍ Müller, Axel H. E. ;Lochmann, Lubomír ;Trekoval, Jiři 📂 Article 📅 1986 🏛 Wiley (John Wiley & Sons) ⚖ 318 KB

The rate constants of polymerization and cyclization and the equilibrium constants of polymerization are calculated from kinetic data of the anionic oligomerization of methyl methacrylate initiated by methyl a-lithioisobutyrate in THF at 25 "C, and of the "disproportionation" of living oligomers. Th