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Dependence of the propagation rate constants on the degree of polymerization in the initial stage of the anionic polymerization of methyl methacrylate in tetrahydrofuran

✍ Scribed by Tsvetanov, Kh.; Mueller, A. H. E.; Schulz, G. V.

Book ID
127072797
Publisher
American Chemical Society
Year
1985
Tongue
English
Weight
669 KB
Volume
18
Category
Article
ISSN
0024-9297

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Equilibria in the anionic polymerization
Equilibria in the anionic polymerization of methyl methacrylate, 1. Chain-length dependence of the rate and equilibrium constants
✍ MΓΌller, Axel H. E. ;Lochmann, LubomΓ­r ;Trekoval, JiΕ™i πŸ“‚ Article πŸ“… 1986 πŸ› Wiley (John Wiley & Sons) βš– 318 KB

The rate constants of polymerization and cyclization and the equilibrium constants of polymerization are calculated from kinetic data of the anionic oligomerization of methyl methacrylate initiated by methyl a-lithioisobutyrate in THF at 25 "C, and of the "disproportionation" of living oligomers. Th