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Effect of Lithium Perchlorate on the Kinetics of the Anionic Polymerization of Methyl Methacrylate in Tetrahydrofuran

✍ Scribed by Baskaran, D.; Müller, Axel H. E.; Sivaram, S.

Book ID
127318628
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
81 KB
Volume
32
Category
Article
ISSN
0024-9297

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Effect of LiClO4 and LiCl Additives on the Kinetics of Anionic Polymerization of Methyl Methacrylate in Toluene-Tetrahydrofuran Mixed Solvent
✍ Mahua G. Dhara; Durairaj Baskaran; Swaminathan Sivaram 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 English ⚖ 141 KB

## Abstract The kinetics of anionic polymerization of MMA has been studied at −78 °C in toluene‐THF (9:1 v/v) using 1,1′‐diphenylhexyl lithium as initiator in the presence of lithium perchlorate and lithium chloride as Lewis acid additives. The control of the polymerization is lost in the absence o