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Kinetic Investigation on Metal Free Anionic Polymerization of Methyl Methacrylate Using Tetraphenylphosphonium as the Counterion in Tetrahydrofuran

✍ Scribed by Baskaran, D.; Müller, Axel H. E.


Book ID
126258631
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
169 KB
Volume
30
Category
Article
ISSN
0024-9297

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## Abstract The kinetics of anionic polymerization of MMA has been studied at −78 °C in toluene‐THF (9:1 v/v) using 1,1′‐diphenylhexyl lithium as initiator in the presence of lithium perchlorate and lithium chloride as Lewis acid additives. The control of the polymerization is lost in the absence o