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Rate Constants for the β-Elimination of Tosyl Radical from a Variety of Substituted Carbon-Centered Radicals

✍ Scribed by Timokhin, Vitaliy I.; Gastaldi, Stéphane; Bertrand, Michèle P.; Chatgilialoglu, Chryssostomos


Book ID
126917527
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
97 KB
Volume
68
Category
Article
ISSN
0022-3263

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The Tris(trimethylsilyl)silane/Thiol Red
✍ Chryssostomos Chatgilialoglu 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 German ⚖ 125 KB

## Abstract An extension of the well‐known ‘free‐radical‐clock’ methodology is described that allows one to determine the rate constants of carbon‐centered radicals with a variety of thiols by using the tris(trimethylsilyl)silane/thiol couple as a reducing system. A total of 20 rate constants for t