## Abstract An extension of the well‐known ‘free‐radical‐clock’ methodology is described that allows one to determine the rate constants of carbon‐centered radicals with a variety of thiols by using the tris(trimethylsilyl)silane/thiol couple as a reducing system. A total of 20 rate constants for t
Rate Constants for the β-Elimination of Tosyl Radical from a Variety of Substituted Carbon-Centered Radicals.
✍ Scribed by Vitaliy I. Timokhin; Stephane Gastaldi; Michele P. Bertrand; Chryssostomos Chatgilialoglu
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 52 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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