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Rate constants for the reactions of CCI (X̃2Π) with a number of methylhalosilanes

✍ Scribed by F.C. James; H.K.J. Choi; O.P. Strausz; T.N. Bell

Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
261 KB
Volume
73
Category
Article
ISSN
0009-2614

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✦ Synopsis

Recerved 18 Apnl1980

Rate constants for the gas-phase reacttons of Ccl& 2n) WI~JI a number of methylhalosilanes of general formula hfexClySdJ4_(x+y) have been obtamed by krnetic absocptron spectroscopy. The rate constants are strongly mfluenced by substrtuuon of chlorme for the methyl groups of tnmethylsdane. falhng from a value of (2 8 f 0.2) X 10' M-' s-l for Me&H to C 4 X IO6 hl-' s-t for Cl&H Ccl@ *n) does not react wth SI-CI, SI-F or C-Cl bonds

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