Rate constants for the reaction of O(3P) atoms with benzene and toluene over the temperature range 299–440 K
✍ Scribed by R. Atkinson; J.N. Pitts Jr.
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 499 KB
- Volume
- 63
- Category
- Article
- ISSN
- 0009-2614
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Kate constants for the reaction O(3P) + SO2 + M have been determined over the temperature range of 299"-440"K, using a flash photolysis-NO2 chemiluminescence technique. For M=Ar, the Arrhenius expression k2Ar = 3.1 X 10-32e-'2005\*3")'RT cm6/molec2 ~ sec was obtained. A t room temperature kqAr = (1.
Absolute rate constants for the reaction of SiH4 with O(3P) atoms and OH radicals have been determined over the temperature range 297"438'K using flash photolysis-NO:! chemiluminescence and flash photolysis-resonance fluorescence techniques, respectively. The Arrhenius expressions obtained are wher
Rate constants for the reaction of OH radicals vlith COS. CSz and CII~SCHJ, which are invo!ved in the glohal sulfur cycle, iI;IVC been determined over the temperature range 299-430 K uGng a flash ps hotolysis-resonance fluorcsccnu: tcchmque. For COS and CS2 upper limits at room tcmyzraturc of k(COS)
## Abstract The rate constant of the reaction Cl + CH~3~OH (__k__~1~) has been measured in 500–950 Torr of N~2~ over the temperature range 291–475 K. The rate constant determination was carried out using the relative rate technique with C~2~H~6~ as the reference compound. Experiments were performed
Rate constants for the reaction between Cl atoms and HOh'02 were measured at 243,264. and 198 I( by the flash photolysis resonance fluorescence technique\_ The data can be fit to the Arrhenius expression R1 = 5.1 X lo-" esp(-1700/T) cm3 m01ecule~~ s-' snd indicate that the reaction is unimportanr in