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Rate constants for the reaction of (sP) atoms with SO2 (M = N2O) over the temperature range 299–392 K

✍ Scribed by R. Atkinson; J.N. Pitts Jr.


Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
360 KB
Volume
29
Category
Article
ISSN
0009-2614

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📜 SIMILAR VOLUMES


Kinetics of the reaction O(3P) + SO2 + M
✍ R. Atkinson; J. N. Pitts Jr. 📂 Article 📅 1978 🏛 John Wiley and Sons 🌐 English ⚖ 480 KB

Kate constants for the reaction O(3P) + SO2 + M have been determined over the temperature range of 299"-440"K, using a flash photolysis-NO2 chemiluminescence technique. For M=Ar, the Arrhenius expression k2Ar = 3.1 X 10-32e-'2005\*3")'RT cm6/molec2 ~ sec was obtained. A t room temperature kqAr = (1.

Rate constants for the reaction of OH ra
✍ R. Atkinson; R.A. Perry; J.N. Pitts Jr. 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 387 KB

Absolute rate constants. k2. for the reaction of OH radicals with 2-methyl-2-butene have been determined over the temperature range 297-425 K usinp P flash photolysis-resonance fluorescence technique. The Arrhenius expression obtained was & = 3.6 X lo-" exp [(450 +-400)/RTJ cm3 moleculeS1 ~8.

Rate constants for the reaction of OH ra
✍ R. Atkinson; R.A. Perry; J.N. Pitts Jr. 📂 Article 📅 1978 🏛 Elsevier Science 🌐 English ⚖ 414 KB

Rate constants for the reaction of OH radicals vlith COS. CSz and CII~SCHJ, which are invo!ved in the glohal sulfur cycle, iI;IVC been determined over the temperature range 299-430 K uGng a flash ps hotolysis-resonance fluorcsccnu: tcchmque. For COS and CS2 upper limits at room tcmyzraturc of k(COS)