Rate constants for the reaction of (sP) atoms with SO2 (M = N2O) over the temperature range 299–392 K
✍ Scribed by R. Atkinson; J.N. Pitts Jr.
- Publisher
- Elsevier Science
- Year
- 1974
- Tongue
- English
- Weight
- 360 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0009-2614
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📜 SIMILAR VOLUMES
Kate constants for the reaction O(3P) + SO2 + M have been determined over the temperature range of 299"-440"K, using a flash photolysis-NO2 chemiluminescence technique. For M=Ar, the Arrhenius expression k2Ar = 3.1 X 10-32e-'2005\*3")'RT cm6/molec2 ~ sec was obtained. A t room temperature kqAr = (1.
Absolute rate constants. k2. for the reaction of OH radicals with 2-methyl-2-butene have been determined over the temperature range 297-425 K usinp P flash photolysis-resonance fluorescence technique. The Arrhenius expression obtained was & = 3.6 X lo-" exp [(450 +-400)/RTJ cm3 moleculeS1 ~8.
Rate constants for the reaction of OH radicals vlith COS. CSz and CII~SCHJ, which are invo!ved in the glohal sulfur cycle, iI;IVC been determined over the temperature range 299-430 K uGng a flash ps hotolysis-resonance fluorcsccnu: tcchmque. For COS and CS2 upper limits at room tcmyzraturc of k(COS)