Reactions of HCCCO and NCCO radicals with O 2 have been studied by a combination of pulsed laser photolysis and photoionization mass spectrometry. HCCCO was produced by 193-nm photolysis of methylpropiolate or 3-butyn-2-one, and NCCO was formed by 193-nm photolysis of acetylcyanide. The rate constan
Rate constants for the interaction of trifluoromethyl radicals with oxygen and fluorine
โ Scribed by Arutyunov, V. S. ;Gorshenev, S. I. ;Chaikin, A. M.
- Book ID
- 112691097
- Publisher
- Springer
- Year
- 1977
- Tongue
- English
- Weight
- 202 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0133-1736
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The flash photolyses of azo-n-propane and azoisopropane in the presence of oxygen have been studied by kinetic spectroscopy. The transient absorption spectra observed in the region of 210-290 nm are assigned to the n-propylperoxy and isopropylperoxy radicals. For the n-propylperoxy radical, cmax = 1
Rate constants for the combination of methyl radicals with NO and 0 2 have been measured by flash photolysis of azomethane coupled with product analysis by gas chromatography. Values of the rate constants have been obtained over the pressure regiofi from 50 to 700 torr with He, NP, and Ar as quenchi