Using a relative rate method, rate constants have been measured for the gasphase reactions of the OH radical with the dibasic esters dimethyl succinate The rate constants ob-298 ฯฎ 3 K. tained were (in units of ): dimethyl succinate, dimethyl 10 cm molecule s 1.4 ฯฎ 0.6; glutarate, and dimethyl adip
Rate Constants for the Gas-Phase Reactions of the OH Radical with Selected Carbamates and Lactates
โ Scribed by Kwok, Eric S. C.; Aschmann, Sara M.; Atkinson, Roger
- Book ID
- 126896707
- Publisher
- American Chemical Society
- Year
- 1996
- Tongue
- English
- Weight
- 312 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0013-936X
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๐ SIMILAR VOLUMES
3-Methylfuran has been identified as a product of the gas-phase reaction of the OH radical with isoprene, and under simulated atmospheric conditions a formation yield of 0.044 -t 0.006 was determined. In an analogous manner, the OH radical reaction with 1,3-butadiene formed furan with a yield of 0.0
The gas-phase reaction of NO 3 radicals with selected oxiranes has been studied in a flow system at T = 295 + 2 K in the pressure range 3.4-50 mbar using N 2 as carrier gas. The analysis of the organics was performed by means of on-line connected GC-FID. Rate constants were obtained with the relativ