Rate constants for the cyclisation of some aryl radicals bearing unsaturated ortho-substituents
β Scribed by Abeywickrema, Anil N.; Beckwith, Athelstan L. J.
- Book ID
- 120214572
- Publisher
- The Royal Society of Chemistry
- Year
- 1986
- Tongue
- English
- Weight
- 226 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0022-4936
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π SIMILAR VOLUMES
Rate constants of OH radical reaction with some amino polycarboxylic acids (APCAs) such as EDTA, DTPA, HEDTA, NTA, and HIDA have been determined at different pHs using pulse radiolysis competition kinetics method with thiocyanate as the reference solute. The rate constants varied with pH (possibly d
Rate constants have been measured in aqueous solutions for the reactions of the carbonate radical, COs'-, with several saturated alcohols and one cyclic ether as a function of temperature. Arrhenius pre-exponential factors ranged from 2 X lo8 to 1 X lo9 e mol-' s-l and activation energies ranged fr