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Rate Constants for Reactions of Alkyl Radicals with Water and Methanol Complexes of Triethylborane

โœ Scribed by Jin, Jing; Newcomb, Martin

Book ID
126079473
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
94 KB
Volume
72
Category
Article
ISSN
0022-3263

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๐Ÿ“œ SIMILAR VOLUMES

Rate constants for the reactions of alky
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โœ J. A. Hawari; P. S. Engel; D. Griller ๐Ÿ“‚ Article ๐Ÿ“… 1985 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 220 KB ๐Ÿ‘ 1 views

An electron paramagnetic resonance (EPR) technique was used to show that simple alkyl radicals readily abstract hydrogen from l,4-cyclohexadiene. Rate constants for the reaction were ca. 104-105 M-' s-' at 300 K and activation energies 5-7 kcal mol-'. For the stabilized radicals, ally1 and benzyl, t

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Relative rate constants for the reactions of hydroxyl radicals with a series of alkyl substituted olefins were measured by competitive reactions between pairs of olefins a t 298 r 2 K and 1 atmospheric pressure. Hydroxyl radicals were produced by the photolysis of H,O, with 254-nm irradiation. The o