𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Rate Constants for Reactions of (Perhaloalkyl)peroxyl Radicals with Alkenes in Methanol

✍ Scribed by Shoute, L. C. T.; Alfassi, Z. B.; Neta, P.; Huie, R. E.


Book ID
111940781
Publisher
American Chemical Society
Year
1994
Tongue
English
Weight
455 KB
Volume
98
Category
Article
ISSN
0022-3654

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


Rate constants for reactions of perfluor
✍ G. S. Nahor; P. Neta πŸ“‚ Article πŸ“… 1991 πŸ› John Wiley and Sons 🌐 English βš– 334 KB

Perfluorobutylperoxyl radicals were produced by radiolytic reduction of perf luorobutyl iodide in aerated methanol solutions. Rate constants for the reactions of this peroxyl radical with various organic compounds were determined by kinetic spectrophotometric pulse radiolysis. The rate constants for

Absolute rate constants for the addition
✍ J. Q. Wu; H. Fischer πŸ“‚ Article πŸ“… 1995 πŸ› John Wiley and Sons 🌐 English βš– 753 KB

Absolute rate constants and their temperature dependencies were determined for the addition of hydroxymethyl radicals ( C H 2 0 H ) to 20 monoor 1,l-disubstituted alkenes (CH2 = C X Y ) in methanol by time-resolved electron spin resonance spectroscopy. With the alkene substituents the rate constants

Rate constants and transition-state geom
✍ Evgeny Denisov; Crissostomos Chatgilialoglu; Aleksander Shestakov; Taisa Denisov πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons 🌐 English βš– 149 KB

## Abstract Enthalpy, activation energy, and rate constant of 9 alkyl, 3 acyl, 3 alkoxyl, and 9 peroxyl radicals with alkanethiols, benzenethiol, and L‐cysteine are calculated. The intersection parabolas model is used for activation energy calculations. Depending on the structure of attacking radic