Flash photolysis/time-resolved UV absorption measurements of the rate constants for the title reactions are reported over the temperature range 2 lo-253 K. The photolysis of F2/CF,H/03/02/N, gas mixtures reveals that the formation of CF302 and CF,O radicals has no measurable effect on the ozone conc
Rate constants for one-electron oxidation by the CF3O2., CCl3O2., and CBr3O2. radicals in aqueous solutions
โ Scribed by Robert E. Huie; D. Brault; P. Neta
- Book ID
- 113136990
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 444 KB
- Volume
- 62
- Category
- Article
- ISSN
- 0009-2797
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Using a pulse radiolysis UV absorption technique and subsequent simulations of experimental NO1 and FNO absorption transients, rate constants for reaction between CF90 and CFsO2 radicals with NO were determined, CFp02+NO+CF,O+N02 (3 ), CF,OtNO~CF,OtFNO(5).k~wasderivedtobe(1.68~0.26)X10~~'cm3molecuIe
The rate constants for the reactions CF302 + NO ~ CF30+NO 2 (1) and CF30+NO~ products (2) have been measured at room temperature using a fast flow reactor associated with a monitoring of CF30 radicals by laser induced fluorescence (LIF); for the measurement of k~, CF30 radicals are prepared by the d
The kinetics of the reactions O( 3 P) ฯฉ CF 2 "CCl 2 and O( 3 P) ฯฉ CF 3 CF "CF 2 were studied at room temperature in a discharge flow tube system. The overall rate constants based on the measured afterglow reactions were (3.10 ฯฎ 0.40) ฯซ 10 ฯช13 and (3.00 ฯฎ 0.60) ฯซ 10 ฯช14 cm 3 molecule ฯช1 s ฯช1 , respec
## Abstract Rate coefficients, __k__, and ClO radical product yields, __Y__, for the gasโphase reaction of O(^1^D) with CClF~2~CCl~2~F (CFCโ113) (__k__~2~), CCl~3~CF~3~ (CFCโ113a) (__k__~3~), CClF~2~CClF~2~ (CFCโ114) (__k__~4~), and CCl~2~FCF~3~ (CFCโ114a) (__k__~5~) at 296 K are reported. Rate coe
Using the pulse radiolysis WV absorption technique and subsequent simulations of experimental absorption transients at and 276 nm, upper limits of the rate constants for the reactions of CF302 and CF,O radicals with ozone were determined at K, CF302 t OI-+CF,Ot 202 (4), CF,O t 03+CF302+02 (5). The u