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Rate constants for hydrogen abstraction reactions of the sulfate radical, SO4-: experimental and theoretical results for cyclic ethers

โœ Scribed by Huie, Robert E.; Clifton, Carol L.; Kafafi, Sherif A.

Book ID
120624844
Publisher
American Chemical Society
Year
1991
Tongue
English
Weight
587 KB
Volume
95
Category
Article
ISSN
0022-3654

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Rate constants for hydrogen abstraction
Rate constants for hydrogen abstraction reactions of the sulfate radical, SO4โˆ’. Alkanes and ethers
โœ Robert E. Huie; Carol L. Clifton ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 451 KB ๐Ÿ‘ 1 views

Rate constants have been determined for the reactions of SO4with a series of alkanes and ethers. The SO, radical was produced by the laser-flash photolysis of persulfate, SZO: -. For methane, only an upper limit of 1 x lo6 M-' s-\* could be determined. For ethane, propane, and 2-methylpropane, rate

Rate constants for hydrogen abstraction
Rate constants for hydrogen abstraction reactions of the sulfate radical, SO4โˆ’. Alcohols
โœ Carol L. Clifton; Robert E. Huie ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 504 KB

Rate constants have been determined for the reactions of SO4with a series of alcohols, including hydrated formaldehyde. The SO,radical was produced by the laserflash photolysis of persulfate, Sz02-. Rate constants for the reactions of SO4with alcohols range from 1.0 x lo7 for methanol to 3.4 x 10' M

Rate constants for some hydrogen abstrac
Rate constants for some hydrogen abstraction reactions of the carbonate radical
โœ Carol L. Clifton; Robert E. Huie ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 243 KB ๐Ÿ‘ 1 views

Rate constants have been measured in aqueous solutions for the reactions of the carbonate radical, COs'-, with several saturated alcohols and one cyclic ether as a function of temperature. Arrhenius pre-exponential factors ranged from 2 X lo8 to 1 X lo9 e mol-' s-l and activation energies ranged fr

Rate constants for hydrogen abstraction
Rate constants for hydrogen abstraction reactions by the hydroperoxyl radical from methanol, ethenol, acetaldehyde, toluene, and phenol
โœ Mohammednoor Altarawneh; Ala'A H. Al-Muhtaseb; Bogdan Z. Dlugogorski; Eric M. Ke ๐Ÿ“‚ Article ๐Ÿ“… 2011 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 381 KB ๐Ÿ‘ 1 views

An important step in the initial oxidation of hydrocarbons at low to intermediate temperatures is the abstraction of H by hydroperoxyl radical (HO(2)). In this study, we calculate energy profiles for the sequence: reactant + HO(2) โ†’ [complex of reactants] โ†’ transition state โ†’ [complex of products] โ†’