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Temperature dependence of the rate constants for reactions of the sulfate radical, SO4-, with anions

✍ Scribed by Huie, Robert E.; Clifton, Carol L.

Book ID: 120554856
Publisher: American Chemical Society
Year: 1990
Tongue: English
Weight: 850 KB
Volume: 94
Category: Article
ISSN: 0022-3654
DOI: 10.1021/j100386a015

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Rate constants have been determined for the reactions of SO4with a series of alcohols, including hydrated formaldehyde. The SO,radical was produced by the laserflash photolysis of persulfate, Sz02-. Rate constants for the reactions of SO4with alcohols range from 1.0 x lo7 for methanol to 3.4 x 10' M

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Rate constants have been measured for the reactions of the sulfate radical, SO4'-, with alkanes, alkenes, alcohols, ethers, and amines in 95% acetonitrile solution. The rate constants were in the range of lo6 L mol-l s-l for the abstraction reactions and lo7 -lo9 L mol-' s-l for the addition and ele