The rate constants of the reactions of ethoxy (C 2 H 5 O), i-propoxy (i-C 3 H 7 O) and npropoxy (n-C 3 H 7 O) radicals with O 2 and NO have been measured as a function of temperature. Radicals have been generated by laser photolysis from the appropriate alkyl nitrite and have been detected by laser-
Rate Constants as a Function of Temperature and Kinetic Energy for the Reactions of Cl - with C 2 H 5 Br and n -C 3 H 7 Br
β Scribed by Viggiano, Albert A.; Midey, Anthony J.
- Book ID
- 125990645
- Publisher
- American Chemical Society
- Year
- 2000
- Tongue
- English
- Weight
- 48 KB
- Volume
- 104
- Category
- Article
- ISSN
- 1089-5639
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π SIMILAR VOLUMES
Absolute rate constants a t room temperature for the metathesis reaction C~FS + Br2 C2FSBr + Br and nd3F7 + Br2 CzFTBr + Br have been measured under V L P P conditions: The radicals were generated through collisionless infrared-multiphoton decomposition of the corresponding iodides by irradiation f
## Abstract The kinetics of the C~2~H~5~ + Cl~2~, __n__βC~3~H~7~ + Cl~2~, and __n__βC~4~H~9~ + Cl~2~ reactions has been studied at temperatures between 190 and 360 K using laser photolysis/photoionization mass spectrometry. Decays of radical concentrations have been monitored in timeβresolved measu