3-Methylfuran has been identified as a product of the gas-phase reaction of the OH radical with isoprene, and under simulated atmospheric conditions a formation yield of 0.044 -t 0.006 was determined. In an analogous manner, the OH radical reaction with 1,3-butadiene formed furan with a yield of 0.0
Rate Constants and Products of the OH Reaction with Isoprene-Derived Epoxides
β Scribed by Jacobs, Michael I.; Darer, Adam I.; Elrod, Matthew J.
- Book ID
- 127287730
- Publisher
- American Chemical Society
- Year
- 2013
- Tongue
- English
- Weight
- 666 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0013-936X
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π SIMILAR VOLUMES
## Abstract Rate constants for the gasβphase reactions of the hydroxyl radical with the biogenic hydrocarbons, Ξ²βmyrcene and isoprene, were measured using the relative rate technique over the temperature range 313β413 K and at βΌ1 atm total pressure. OH was produced by the photolysis of H~2~O~2~, an
The kinetics of the reactions of hydroxy radicals with cyclopropane and cyclobutane has been investigated in the temperature range of 298-492 K with laser flash photolysidresonance fluorescence technique. The temperature dependence of the rate constants is given by k l = (1.17 ? 0.15) x T3'' exp[-(1