Kcccivcd 7 hlarch 1977 The rate constant Ior the rrnction Br + 0~ -BrO + 02 has been mcawrcd over the tempcraturc rdrye 224 to 522 EC in a dxhargc llow systcni ucmk a IKISF spcctrornctcr a~ B detector. Rcsultg, c\pre%scd in the form kr = (3.34 c O-40) X IO-\*' X cxp[ -(978 1. 36)/T] cn13 s-' , arc c
Rate constant for the reaction of bromine atoms with ethane: Kinetic and thermochemical implications
✍ Scribed by Zügner, Gábor L. ;Szilágyi, István ;Nádasdi, Rebeka ;Dóbé, Sándor ;Zádor, Judit ;Márta, Ferenc
- Publisher
- Springer
- Year
- 2008
- Tongue
- English
- Weight
- 150 KB
- Volume
- 95
- Category
- Article
- ISSN
- 0133-1736
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## Abstract The rate constant for the reaction of Br + O~3~ → BrO + O~2~ has been measured at four temperatures from 234 to 360 K by the technique of discharge flow coupled with resonance‐fluorescence detection of bromine atoms. The measured rate constants obey the Arrhenius expression __k__ = (9.4
The O(3P) + CION reaction has been studicd in a fast flow system over the temperature range from 213 to 295 K, using the air-aftereIow technique for the detection of oxygen atoms under pseudo first order conditions. A value of (3.4 z 0.6) x 10-" exp[(-840 + 60)/T] cm3 molecule-' s-' has been obtaine