The reaction of atomic chlorine with neopentane was studied in the gas phase with the Very Low Pressure Reactor (VLPR) technique over the temperature range 273-333 K. The absolute reaction rate was found to be temperature-independent, and the average rate constant was kl = (1.11 5 0.13) X cm3 molecu
Relative-rate kinetic study of the reaction of bromine atom with neopentane
✍ Scribed by Imrik, K. ;Dóbé, S. ;Bérces, T.
- Publisher
- Springer
- Year
- 1998
- Tongue
- English
- Weight
- 246 KB
- Volume
- 65
- Category
- Article
- ISSN
- 0133-1736
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The relative rate technique has been used to determine rate constants for the reaction of bromine atoms with a variety of organic compounds. Decay rates of the organic species were measured relative to z-butane or acetaldehyde or both. Using rate constants of 1.74 x and 3.5 x lo-'' cm3 rnolecule-'s-
Kcccivcd 7 hlarch 1977 The rate constant Ior the rrnction Br + 0~ -BrO + 02 has been mcawrcd over the tempcraturc rdrye 224 to 522 EC in a dxhargc llow systcni ucmk a IKISF spcctrornctcr a~ B detector. Rcsultg, c\pre%scd in the form kr = (3.34 c O-40) X IO-\*' X cxp[ -(978 1. 36)/T] cn13 s-' , arc c