Rate coefficients for the chemical reactions of CH2F2, CHClF2, CH2FCF3 and CH3CCl3 with O(1D) at 298K
โ Scribed by Nilsson, E.J.K.; Andersen, V.F.; Nielsen, O.J.; Johnson, M.S.
- Book ID
- 121715530
- Publisher
- Elsevier Science
- Year
- 2012
- Tongue
- English
- Weight
- 281 KB
- Volume
- 554
- Category
- Article
- ISSN
- 0009-2614
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๐ SIMILAR VOLUMES
## Abstract Rate constants for the gasโphase reactions of CH~3~OCH~2~CF~3~ (__k__~1~), CH~3~OCH~3~ (__k__~2~), CH~3~OCH~2~CH~3~ (__k__~3~), and CH~3~CH~2~OCH~2~CH~3~ (__k__~4~) with NO~3~ radicals were determined by means of a relative rate method at 298 K. NO~3~ radicals were prepared by thermal d
Excess molar volumes V E m of the ternary mixture {x1CH3(CH2)3OH+x2CH3(CH2)4CH3 + (1-x1-x2)CH3(CH2)3NH2} at the temperatures 298.15 K and 313.15 K, and the binary mixtures {xCH3(CH2)3OH + (1-x)CH3(CH2)3NH2}, {xCH3(CH2)4CH3 + (1-x)CH3(CH2)3NH2} at T=313.15 K have been determined from density measurem
Excess molar enthalpies at the temperature 298.15 K were measured for CH2)nCH3} (n = 9, 12), and {x2CH3(CH2)4CH3 + (1-x2)CH3(CH2)n-2CH3} (n=9, 12), using a Calvet microcalorimeter. The experimental results were compared with those calculated by using the Nitta-and-Chao model.
Rate constants for the reactions of OH radicals and Cl atoms with CH,CH,NO>, CH,CH,CH,NO,, CH3CH2CH2CHzN02, and CH,CH2CH2CH,CH2N02 have been determined at 295+3 K and a total pressure of approximately 1 atm. The OH rate data were obtained using both the absolute rate technique of pulse radiolysis co