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Random-Coil Configurations of the Polyformals [CH 2 O(CH 2 ) δ O-]. 3. The Temperature Coefficient of the Unperturbed Dimensions of Poly(1,3-dioxolane) [CH 2 O(CH 2 ) 2 O-]

✍ Scribed by Rahalkar, R. R.; Mark, J. E.; Riande, E.

Book ID: 126818897
Publisher: American Chemical Society
Year: 1979
Tongue: English
Weight: 261 KB
Volume: 12
Category: Article
ISSN: 0024-9297
DOI: 10.1021/ma60070a053

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Methylperoxy radicals were generated by the flash photolysis of azomethane-oxygen mixtures. The observed broadband spectrum of the CH302 radical is similar, but not identical to those reported previously. The CH:302 decay followed second-order kinetics a t high CH:jOz concentrations with k4, = (2.5