## Linewidths of isotropic Raman bands of benzonitrile at 2223 and 452 cm-' were measured as a function of concentration in benzene solution. Experimental results have been compared with those calculated on the basis of the Fischer-Laubereau binary-collision dephasing model and the Knapp-Fischer c
Raman study of vibrational relaxation of benzene in solution
β Scribed by K. Tanabe; J. Jonas
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- English
- Weight
- 342 KB
- Volume
- 53
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
β¦ Synopsis
Measurements of the isotropic
Raman spectra of the VI (alg) C-H stretch& 0 band of benzene in various solvents are reported. The observed band width is interpreted in terms of the vibrational dephasing model modified for use in bii mix-tures_
π SIMILAR VOLUMES
The htixvidths 01 the symmetricC-H and C-D stretching modes of liquid C6H6, C6D,. symC6D3H3. p-C6H2D1, P-%%Dz. CgHDg, and C6HsD are reported. Their temperature dependence IS mezvxred in nearly the whole liquid rang There is no coincidence with present rek~~ation theones.
## Abstract The vibrational relaxation and molecular reorientational processes in liquids have been studied in some carbonylβcontaining molecules using the acetonitrile (ACN) solvent. The vibrational and reorientational processes have been studied in correspondence with correlation times. The scree